84) The chemistry of the 2‐phosphaethynolate anion. J. M. Goicoechea*, H. Grützmacher*, Angew. Chem. Int. Ed. 2018, 57, 16968–16994.
83) Flexible and versatile pincer-type PGeP and PSnP ligand frameworks. S. Bestgen, N. H. Rees, J. M. Goicoechea*, Organometallics 2018, 37, 4147–4155.
82) Synthesis and reactivity of rare-earth metal phosphaethynolates. S. Bestgen, Q. Chen, N. H. Rees, J. M. Goicoechea*, Dalton Trans. 2018, 47, 13016–13024.
81) On the viability of catalytic turnover via Al–O/B–H metathesis: the reactivity of β‐diketiminate aluminium hydrides towards CO2 and boranes. A. Caise, D. Jones, E. L. Kolychev, J. Hicks, J. M. Goicoechea, S. Aldridge*, Chem. Eur. J. 2018, 24, 13624–13635.
80) Phosphinecarboxamide as an unexpected phosphorus precursor in the chemical vapour deposition of zinc phosphide thin films. S. V. F. Beddoe, S. D. Cosham, A. N. Kulak, A. R. Jupp, J. M. Goicoechea, G. Hyett*, Dalton Trans. 2018, 47, 9221–9225.
79) The heterocubane [TerSnAs]4. A.Hinz*, J. M. Goicoechea*, Dalton Trans. 2018, 47, 8879–8883.
78) A general synthesis of phosphorus‐ and arsenic‐containing analogues of the thio‐ and seleno‐cyanate anions. F. Tambornino, A. Hinz, R. Köppe, J. M. Goicoechea*, Angew. Chem. Int. Ed. 2018, 57, 8230–8234.
77) Intercepting a transient phosphino-arsinidene. A. Hinz, M. Hansmann, G. Bertrand*, J. M. Goicoechea*, Chem. Eur. J. 2018, 24, 9514–9519.
76) Synthesis, structure and reaction chemistry of a nucleophilic aluminyl anion. J. Hicks, P. Vasko, J. M. Goicoechea*, S. Aldridge*, Nature 2018, 557, 92–95. Highlighted in: Angew. Chem. Int. Ed. 2018, 57, 8818–8820.
75) Limitations of steric bulk: Towards phospha‐germynes and phospha‐stannynes. A. Hinz*, J. M. Goicoechea*, Chem. Eur. J. 2018, 24, 7358–7363.
74) Deprotonation of group 14 metal amide complexes bearing ditopic carbanionic N-heterocyclic carbene ligands. Constitutional isomerism and dynamic behavior. J. B. Waters, L. S. Tucker, J. M. Goicoechea*, Organometallics 2018, 37, 655–664. Invited submission “Organometallic Chemistry in Europe” issue.
73) An isolable phosphaethynolato-borane and its reactivity. D. W. N. Wilson, A. Hinz, J. M. Goicoechea*, Angew. Chem. Int. Ed. 2018, 57, 2188–2193.
72) Synthesis and reactivity of nickel-stabilised µ2:η2,η2-P2, As2 and PAs units. G. Hierlmeier, A. Hinz, R. Wolf*, J. M. Goicoechea*, Angew. Chem. Int. Ed. 2018, 57, 431 –436.