Goicoechea Group

123) Pincer‐supported gallium complexes for the catalytic hydroboration of aldehydes, ketones and carbon dioxide. L. Liu, S.-K. Lo, C. D. Smith, J. M. Goicoechea*, Chem. Eur. J. 2021, 27, 17379–17385.

122) Synthesis, structure and reactivity of a cyapho-cyanamide salt. D. Ergöçmen, J. M. Goicoechea*, Angew. Chem. Int. Ed. 2021, 60, 25286–25289.

121) Coinage metal aluminyl complexes: probing regiochemistry and mechanism in the insertion and reduction of carbon dioxide. C. McManus, J. Hicks, X. Cui, L. Zhao*, G. Frenking*, J. M. Goicoechea*, S. Aldridge*, Chem. Sci. 2021, 12, 13458–13468.

120) Thermoneutral N–H bond activation of ammonia by a geometrically constrained phosphine. J. Abbenseth*, O. P. E. Townrow, J. M. Goicoechea*, Angew. Chem. Int. Ed. 2021, 60, 23625–23629.

119) Probing the extremes of covalency in M–Al bonds: Lithium and zinc aluminyl compounds. M. M. D. Roy, J. Hicks, P. Vasko, A. Heilmann, A.-M. Baston, J. M. Goicoechea*, S. Aldridge*, Angew. Chem. Int. Ed. 2021, 60, 22301–22306.

118) Contrasting E−H bond activation pathways of a phosphanyl-phosphagallene. J. Feld, D. W. N. Wilson, J. M. Goicoechea*, Angew. Chem. Int. Ed. 2021, 60, 22057–22061.

117) A phosphorus analog of a bimetallic dinitrogen complex. J. Abbenseth*, and J. M. Goicoechea*, Chem 2021, 7, 1698−1700. Preview article for: Chem 2021, 7, 1952–1962.

116) A cyaphide transfer reagent. D. W. N. Wilson, S. J. Urwin, E. S. Yang, J. M. Goicoechea*, J. Am. Chem. Soc. 2021, 143, 10367–10373.

115) Cluster expansion and vertex substitution pathways in nickel germanide Zintl clusters. O. P. E. Townrow, A. S. Weller*, J. M. Goicoechea*, Chem. Commun. 2021, 57, 7132–7135.

114) Novel primary phosphinecarboxamides derived from diamines. E. N. Faria, A. Jupp, J. M. Goicoechea*, Dalton Trans. 2021, 50, 6991–6996.

113) η³-Coordination and functionalization of the 2-phosphaethynthiolate anion at lanthanum(III). F. A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend, F. Tambornino*, J. M Goicoechea*, S. Hohloch*, Angew. Chem. Int. Ed. 2021, 60, 9534–9539.

112) Phosphine carboxylate – Probing the edge of stability of a carbon dioxide adduct with dihydrogen-phosphide. R. E. Schreiber*, J. M. Goicoechea*, Angew. Chem. Int. Ed. 2021, 60, 3759–3767.

111) The aluminyl anion: A new generation of aluminium nucleophile. J. Hicks*, P. Vasko, J. M. Goicoechea, S. Aldridge, Angew. Chem. Int. Ed. 2021, 60, 1702–1713.

110) Partnering a three‐coordinate gallium cation with a hydroborate counter‐ion for the catalytic hydrosilylation of CO₂. A. Caise, J. Hicks, M. A. Fuentes, J. M. Goicoechea, S. Aldridge*, Chem. Eur. J. 2021, 27, 2138–2148.