153) Syntheses, Geometric and Electronic Structures of Inorganic Cumulenes. J. Tang, C. Hu, A. E. Crumpton, M. Dietz, D. Sarkar, L. P. Griffin, J. M. Goicoechea*, S. Aldridge* J. Am. Chem. Soc. 2024, 146, 30778–30783. Highlighted in: Nat. Synth. 2024, 3, 1441.
152) Mixed-Valence Iron Complexes Containing End-On Bridging Cyaphide Ions. E. S. Yang, A. García-Romero, C. Hu, J. Fletcher, C. M. Thomas, J. M. Goicoechea*, J. Am. Chem. Soc. 2024, 146, 29207–29213.
151) A Transient Iron Carbide Generated by Cyaphide Cleavage. D. C. Wannipurage, E. S. Yang, A. D. Chivington, J. Fletcher, D. Ray, N. Yamamoto, M. Pink, J. M. Goicoechea*, J. M. Smith* J. Am. Chem. Soc. 2024, 146, 27173–27178.
150) Isolation and characterization of a two-coordinate phosphinidene oxide. C. Hu, N. H. Rees, M. Pink, J. M. Goicoechea* Nat. Chem. 2024, 16, 1855–1860.
149) Carbamoylphosphinidene: A Phosphorus Analogue of Carbonyl Nitrene. B. Lu, J. Jiang, L. Wang, A. R. Jupp, J. M. Goicoechea*, S. Liu, Z. Li, M. Zhou, X. Zeng* J. Am. Chem. Soc. 2024, 146, 18699–18705.
148) A Phosphanyl Phosphagermene and its Reactivity. J. Feld, E.S. Yang, S. J. Urwin, J. M. Goicoechea* Chem. Eur. J. 2024, e202401736.
147) Trapping an Elusive Phosphanyl-Phosphaalumene. L. S. Szych, L. Denker, J. Feld, J. M. Goicoechea* Chem. Eur. J. 2024, 30, e202401326.
146) Ligand Centered Reactivity of a Transition Metal Bound Geometrically Constrained Phosphine. A. J. King, J. M. Goicoechea* Chem. Eur. J. 2024, 30, e202400624
145) Softer is Better for Titanium. Molecular Titanium Arsenido Anions Featuring Ti≡As Bonding and a Terminal Parent Arsinidene. M. Bhunia, J. Mohar, C. Sandoval-Pauker, D. Fehn, D.; E. S. Yang, M. Gau, J. M. Goicoechea, A. Ozarowski, J. Krzystek, J. Telser, K. Meyer, D. J. Mindiola*, J. Am. Chem. Soc. 2024, 146, 3609–3614.
144) Metal Influence on Cyaphide-Azide 1,3-Dipolar Cycloaddition Reactions: Aromaticity and Activation Strain. D. González-Pinardo, J. M. Goicoechea*, I. Fernández*, Chem. Eur. 2024, 30, e202303977.
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